a Residual Gas analyzer measure the elements present xray emission spectrometers completely
| aveform at the digitizing rate of the acquisition hardware. A significant portion of the spectrum consists of zeros, but there is some risk in setting a threshold value too high and neglecting to store some of the signal in the data file. If the data burden is not too great, it would probably make sense to store each entire waveform rather than trying to filter it.
Ion Time-of-Flight Spectrometer (Wiley McLaren type) The ion time-of-flight spectrometer acquires data using the same principle as the electron time-of-flight spectrometers; a signal is acquired as a function of time following photoionization of the sample by the FEL radiation. In the case of the ion TOF, the flight time is proportional to the square root of the mass-to-charge ratio, m/q, of the ion. The flight time for ions is considerably longer than it is for electrons (depending entirely on the length of the flight tube and the accelerating voltages used), and subsequently, less temporal resolution is required from the digitizing electronics. Flight times of up to 1ms should be accessible with the electronics, although in most situations, much shorter flight times will be necessary. Temporal resolution of 0.5ns should be sufficient.
A further complication arises when we want to use the electron and ion spectrometers at the same time. A high voltage pulse must be applied to the interaction region at some time (on the order of 100ns) after the FEL pulse photoionizes the sample. Electrons will quickly depart the interaction region while no electric field is present. Ions, which move much more slowly, will remain in the interaction region in the absence of electrostatic repulsion arising from high charge densities, and can be swept out into the ion spectrometer with a high voltage pulse. A delayed trigger must therefore be implemented for the pulse generator.
This instrument may also be used for a final focus of the optics. After the diagnostics have been used to focus the beam in the interaction region, a scan may be done using the ion TOF as the read-back for the focus optics. Ion Imaging Spectrometer The imaging ion spectrometer measures the momenta of ions by imaging the intersection of the expanding sphere of ions with the flat detector. The image consists of rings of intensity corresponding to the velocity of the ions (with ions expand |
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